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Why can a 12v 100Ah battery not be connected in series with a 12V 200Ah battery? Can you elaborate on what would happen in the cases of lead/acid, Gel and LiFePO4 batteries?

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Swapping Out Lead Acid to LiFePO4 batteries. Is it really that easy? Aolithium 12V100Ah-4S battery

Hi, I bought my dad a 100ah 12v lifepo4 battery for his off grid cabin because he had 2 50ah everstart lead acid deep cycle batteries that are weak and 10 y/o

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AOLITHIUM 51.2V 100Ah LiFePO4 Lithium Battery, 4 Pack 5120Wh Built-in 100A BMS Lithium Batteries, 4000+ Cycles & 15+ Years Lifespan Deep Cycle Battery for RV, Marine, Solar Energy Storage, Camping : : Automotive